Reversible Sm(III)/Sm(II) redox chemistry of an organosamarium(III) complex

被引：23
|
作者：
Wang, J
Amos, RIJ
Frey, ASP
Gardiner, MG
Cole, ML
Junk, PC
机构：
[1] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia
[2] Monash Univ, Sch Chem, Monash, Vic 3800, Australia
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 10期
关键词：
D O I：
10.1021/om050172a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A binuclear samarium(III) complex featuring the mu-eta(1):eta(1)-bound dianion of 1,4-di-tert-butyl-1,4-diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by H-1 and C-13 NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination.
引用
收藏
页码：2259 / 2261
页数：3
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