How anthraquinones can enable aqueous organic redox flow batteries to meet the needs of industrialization

被引:14
|
作者
Fontmorin, Jean-Marie [1 ,2 ]
Guiheneuf, Solene [2 ]
Godet-Bar, Thibault [2 ]
Floner, Didier [1 ]
Geneste, Florence [1 ]
机构
[1] Univ Rennes, CNRS, ISCR, UMR 6226, F-35000 Rennes, France
[2] Kemiwatt, 11 allee Beaulieu CS 50837, F-35708 Rennes 7, France
关键词
Anthraquinone; Ferrocyanide; Aqueous organic redox flow battery; Electrolyte; Electrode pre-treatment; Industrial requirements; Basic medium; STABILITY; CAPACITY; LIFETIME;
D O I
10.1016/j.cocis.2022.101624
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Owing to the importance of storage and its hybridization with renewable energy technologies for the energy transition, a high attention has been paid towards the development of redox flow batteries. Among all different emerging technologies, aqueous organic redox flow batteries (AORFBs) are particularly attrac-tive since the objectives in terms of sustainability, cost and safety issues can be achieved owing to the high possibilities offered by molecular engineering, organometallic and coordi-nation chemistry. Thus, AORFBs based on anthraquinones paired with ferrocyanide in basic medium have been widely developed and are close to reach the performances required for industrial processes. This review aims to focus on the main parameters making possible the integration of anthraquinone derivatives as negolyte in AORFB with a special attention for their implementation in industrial process.
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页数:14
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