Easy Access to (E)-β-Ocimene

被引：15
|
作者：
Yildizhan, Selma [1 ]
Schulz, Stefan [1 ]
机构：
[1] TU Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany
来源：
SYNLETT | 2011年 / 19期
关键词：
terpenoids; Grignard reaction; alkenes; hydrocarbons; coupling; INSECT HERBIVORY; MECHANISM; ALCOHOLS;
D O I：
10.1055/s-0031-1289869
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
beta-Ocimene is one of the most common monoterpenes found in Nature, but a simple and reliable synthesis of the pure E-isomer has been missing. Here, we report a simple procedure involving a Grignard coupling as the key step that allows its synthesis on gram scales. The configuration of the double bond is fixed in the starting material.
引用
收藏
页码：2831 / 2833
页数：3
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