Metal-Organic Frameworks from Edible Natural Products

被引：599

作者：

Smaldone, Ronald A. ^{[1
]}

Forgan, Ross S. ^{[1
]}

Furukawa, Hiroyasu ^{[2
]}

Gassensmith, Jeremiah J. ^{[1
]}

Slawin, Alexandra M. Z. ^{[3
]}

Yaghi, Omar M. ^{[2
]}

Stoddart, J. Fraser ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 46期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

alkali metals; cyclodextrins; metal-organic frameworks; sorption; X-ray diffraction; GAS-CHROMATOGRAPHIC SEPARATION; HYDROGEN STORAGE; CARBON-DIOXIDE; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; XYLENE ISOMERS; HIGH-CAPACITY; ADSORPTION; DESIGN; SELECTIVITY;

D O I：

10.1002/anie.201002343

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Let them eat MOFs: Take a spoonful of sugar (γ-cyclodextrin to be precise), a pinch of salt (most alkali metal salts will suffice), and a swig of alcohol (Everclear fits the bill), and you have a robust, renewable, nanoporous (Langmuir surface area 1320-m2-g-1) metal organic framework for breakfast (CD-MOF-1; see picture, C-gray, O-red, K-purple; yellow sphere: pore). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8630 / 8634

页数：5

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