Phase separation in a system based on cross-linked rubber and low-molecular-mass crystallizable solvent

被引：0
|
作者：
Serenko, OA
Grokhovskaya, TE
Volynskii, AL
Bakeev, NF
机构：
[1] Russian Acad Sci, Inst Synthet Polymer Mat, Moscow 117393, Russia
[2] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1999年 / 41卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Various compositions of cross-linked NR containing different amounts of a linear crystallizable hydrocarbon were studied. At a given content of hydrocarbon in the composition, the corresponding cooling thermograms show two peaks associated with the crystallization of the solvent. Different rates of solvent microsyneresis and crystallization, as well as the dependence of these rates on the solvent concentration in polymer bulk, lead to the appearance of one or two peaks of solvent crystallization in the corresponding cooling thermograms.
引用
收藏
页码：498 / 502
页数：5
相关论文
共 50 条
  • [1] The effect of fluctuation network in cross-linked rubber on the migration of low-molecular-mass component from the system comprising a cross-linked rubber and a low-molecular-mass hydrocarbon
    Serenko, OA
    Grokhovskaya, TE
    Volynskii, AL
    Bakeev, NF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1996, 38 (08): : 1367 - 1372
  • [2] Peculiarities of melting of a low-molecular-mass component in the cross-linked rubber-linear hydrocarbon system
    Serenko, OA
    Grokhovskaya, TE
    Volynskii, AL
    Bakeev, NF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1998, 40 (07): : 1144 - 1149
  • [3] THE EFFECT OF LOW-MOLECULAR-MASS LIQUIDS ON PHYSICAL NETWORK AND VISCOELASTIC PROPERTIES OF CROSS-LINKED AMORPHOUS POLYDIENEURETHANES
    TERESHATOV, VV
    SENICHEV, VY
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1995, 37 (11): : 1888 - 1895
  • [4] SPECIFIC FEATURES OF BLOOMING OF LOW-MOLECULAR-MASS COMPONENT IN (RUBBER POLYMER) (LOW-MOLECULAR-MASS HYDROCARBON) SYSTEMS
    GROKHOVSKAYA, TE
    SERENKO, OA
    VOLYNSKII, AL
    LUKOVKIN, GM
    BAKEEV, NF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1994, 36 (06): : B1016 - B1020
  • [5] Orientation Birefringence of Cross-Linked Rubber Containing Low-Mass Compound
    Kiyama, Ayumi
    Nobukawa, Shogo
    Yamauchi, Masayuki
    PROCEEDINGS OF PPS-30: THE 30TH INTERNATIONAL CONFERENCE OF THE POLYMER PROCESSING SOCIETY, 2015, 1664
  • [6] The effect vulcanizing agent on the exudation of low-molecular-mass component out of vulcanized rubber doped with a low-molecular-mass hydrocarbon
    Serenko, OA
    Grokhovskaya, TE
    Volynskii, AL
    Bakeev, NF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1996, 38 (07): : 1228 - 1233
  • [7] Low molecular weight fenumgreek gum cross-linked gel system
    Jiang, Zhou
    Fang, Bo
    Li, Jin-Sheng
    Lu, Yong-Jun
    Cheng, Wei
    Guan, Chen
    Huadong Ligong Daxue Xuebao /Journal of East China University of Science and Technology, 2005, 31 (05): : 553 - 556
  • [8] Phase Separation of Randomly Cross-Linked Diblock Copolymers
    Wang, Gaoyuan
    Zippelius, Annette
    Mueller, Marcus
    MACROMOLECULES, 2022, 55 (13) : 5567 - 5580
  • [9] PHASE-SEPARATION IN LINEAR AND CROSS-LINKED POLYURETHANES
    RUSSO, R
    THOMAS, EL
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1983, B22 (04): : 553 - 575
  • [10] Metal ion cross-linked nanoporous polymeric membranes with improved organic solvent resistance for molecular separation
    Luo, Xiaofan
    Wang, Zhenggong
    Wu, Shanshan
    Fang, Wangxi
    Jin, Jian
    JOURNAL OF MEMBRANE SCIENCE, 2021, 621
12345