Density narrowing effect in the collisional cluster scattering of the light by gases

被引:1
|
作者
Teboul, V
Le Duff, Y
机构
[1] Univ Angers, Dept Phys, Lab POMA, Unite Mixte Rech CNRS 6136, FR-49045 Angers, France
[2] LRP, F-49080 Bouchemaine, France
关键词
D O I
10.1016/j.cplett.2005.01.090
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The spectral intensities of a collisional cluster scattering band in CF4 gas have been computed using molecular dynamics. Several densities from 20 to 269 Amagat as well as several models of interaction induced polarizability and of intermolecular potential have been studied. A qualitative agreement with experimental results has been obtained showing the narrowing effect of the gas density on the two-body line shape of the collisional cluster Raman band. (C) 2005 Elsevier B.V. All rights reserved.
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页码:199 / 205
页数:7
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