Study of CuxC60 film UV-Vis absorption spectrum

被引:0
|
作者
Wu, WD [1 ]
Zhang, ZW [1 ]
Luo, JS [1 ]
Tang, YJ [1 ]
Zheng, YM [1 ]
Lu, XM [1 ]
Zhao, PJ [1 ]
机构
[1] China Acad Engn Phys, High Temp & High Dens Plasma Key Lab, Sichuan Mianyang 621900, Peoples R China
关键词
CuxC60; film; W-Vis absorb spectrum; electronic structure;
D O I
10.3866/PKU.WHXB20010118
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
in this paper, the formation of the CuxC60 films has been described briefly. The UV-Vis absorption spectrum of CuxC60 film have been discussed in detail, the electronic structure of CuxC60 film is discussed qualitatively. For x < 1, there exists only Cu+ in the CuxC60 films. However, for x = 4, not only Cu+, but also atom-Cu exists in them. In CuxC60 films three strong peaks have been shiffed compared with that of C-60 films. The shift of these strong peaks shows that in the CuxC60 films C-60 molecule accepts only one electron and becomes C-60. Because of the existence of the atom-Cu in the CuxC60 films, in visible region there is a wide peak which is the plasmons resonance absorb peak of the Cu-cluster in it.
引用
收藏
页码:83 / 86
页数:4
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