Loading cobalt phosphate on TaON surface as efficient noble-metal-free co-catalyst for enhanced photocatalytic water oxidation performance

被引:16
|
作者
Liu, Yue [1 ]
Zhou, Yansong [1 ]
Chen, Gang [1 ]
Guo, Tong [1 ]
Wang, Li [1 ]
Huang, Xi [1 ]
Zeng, Wei [1 ]
机构
[1] Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China
关键词
TaON photocatalysts; Cobalt phosphate; Solar energy materials; Cocatalyst-loading; Semiconductor; VISIBLE-LIGHT IRRADIATION; OXYGEN-EVOLVING CATALYST; IN-SITU FORMATION; PHOTOANODE;
D O I
10.1016/j.matlet.2015.02.071
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cobalt phosphate (CoPi) was loaded on the surface of TaON by a photochemical deposition method as an efficient oxygen evolution co-catalyst for the first time. Loading of CoPi showed little effect on the crystal structure and optical properties of TaON. While, the photogenerated charge carriers were efficiently separated in TaON after CoPi loading. Sample of CoPi/TaON (1 wt%) showed enhanced photocatalytic oxygen evolution performance of 1.75 mmol h(-1) g(-1) from water-splitting under visible light irradiation, which is about two times of that for pristine TaON. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:155 / 158
页数:4
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