La[Fe(CN)6] ion pairing in aqueous solution.: A dielectric relaxation study

Complex permittivity spectra of aqueous La[Fe(CN)(6)] solutions at 25 degrees C over the frequency range 0.2 less than or equal to v/GHz less than or equal to 89 are presented. Because of the large association constant of lanthanum ferricyanide, K-A = 5300, and its high ion-pair dipole moment, mu(IP) = 77.7 D, dilute solutions in the range 0.0026 less than or equal to c/mol dm(-3) less than or equal to 0.0485 could be investigated. It is shown that the current models for the analysis of the ion-pair dispersion amplitude are reliable. The data reveal that the formation of contact ion-pairs is at a nearly diffusion controlled rate, and suggest that the ion-pair activity coefficient deviates from ideality. The effective solvation number of the electrolyte is determined from the solvent permittivity.