Harnessing the reactivity of borenium for methane activation

被引：0
|
作者：
DuChane, Christine M. [1 ]
Chen, Jiawei [1 ]
机构：
[1] Cell Press, 50 Hampshire St,5th Floor, Cambridge, MA USA
来源：
CHEM | 2021年 / 7卷 / 07期
关键词：
BORYLATION;
D O I：
10.1016/j.chempr.2021.06.016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methane (CH4) functionalization is an important field that is traditionally dominated by transition-metal catalysis. In this issue of Chem, Wang and colleagues report the exceptional reactivity of an N-heterocyclic carbene (NHC)-stabilized hydroborenium cation that allows for the selective C-H activation of CH4, affording value-added borylated products in a transition-metal-free fashion.
引用
收藏
页码：1691 / 1693
页数：4
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