Kramers turnover theory for a triple well potential

被引:0
|
作者
Pollak, E [1 ]
Talkner, P
机构
[1] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel
[2] Paul Scherrer Inst, CH-5232 Villigen, Switzerland
来源
ACTA PHYSICA POLONICA B | 2001年 / 32卷 / 02期
关键词
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Kramers turnover theory is solved for a particle in a symmetric triple well potential for temperatures above the crossover temperature between tunneling and activated barrier crossing. Comparison with the turnover theory for a double well potential shows that the presence of the intermediate well always leads to a decrease of the reaction rate. At most though, the rate is a factor of two smaller than in the case of a double well potential.
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页码:361 / 371
页数:11
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