Chemical oxidation treatment of petroleum contaminated soil using Fenton's reagent

被引:23
|
作者
Chen, CT
Tafuri, AN
Rahman, M
Foerst, MB
机构
[1] US Environmental Protection Agency, Urban Watershed Management Branch, Edison, NJ 08837 USA
[2] IT Corp, Cincinnati, OH 45246 USA
关键词
Fenton's reagent; underground storage tank; hydrogen peroxide; ferrous sulfate; remediation of contaminated soil; hydroxyl radical; diesel fuel; 2-methylnaphthalene; n-hexadecane;
D O I
10.1080/10934529809376772
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Fenton's reagent, a strong oxidant, was evaluated for suitability to treat soils contaminated with 2-methylnaphthalene (an aromatic compound), n-hexdecane (an aliphatic compound) and diesel fuel (a complicated hydrocarbon mixture). Laboratory-scale results show that Fenton's reagent reacts rapidly with these materials in soil, and will completely mineralize them if enough hydrogen peroxide is added. The effectiveness of the reaction at neutral pH indicates that it should be easier and more cost-effective to apply this technology since no pH adjustment is required prior to soil treatment. Further investigation is required to identify the reaction mechanisms and optimize the parameters to attain the most cost-effective full scale application of this technology.
引用
收藏
页码:987 / 1008
页数:22
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