Synoptic-scale transport of ozone into Southern Ontario

This study focuses on synoptic-scale transport of ozone as it affects Southern Ontario. This process has been analyzed for the summer in 2001, as an example period of a frequent event that usually occurs during summer in this region. The work was carried out using the mesoscale modeling system generation 5 (MM5)/sparse matrix operator kernel emission modeling system (SMOKE)/community multiscale air quality (CMAQ) regional air quality modeling system, together with observational data from monitoring stations located throughout the modeling domain. Other different analyses have been carried out to supply more information apart from that obtained by the modeling system. A back-trajectory cluster methodology was used to evaluate the magnitude of the effects studied and an analysis of wind direction and cloud cover revealed a significant correlation with ozone concentration (R-2 = 0.5-0.6). Synoptic sea-surface level pressure (SLP) patterns were also analyzed to examine other meteorological aspects. The contribution of natural background ozone to the total amount within the region was compared with that from synoptic-scale transport. The influence of emission of pollutants from selected areas on ozone concentrations in Southern Ontario was also analyzed. As relevant results of these analyses, the model predicts that background ozone is the largest contribution to the ground-level ozone concentration during days in which low values were recorded. However, when smog episodes occurred, the model predicts that around 60% of the ozone formed by anthropogenic emissions of pollutants is due to releases from nearby US states. (c) 2007 Elsevier Ltd. All rights reserved.