Transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines

被引：5
|
作者：
Zhang, Hang [1 ]
Wang, Bo [1 ]
Yi, Heng [1 ]
Sun, Tong [1 ]
Zhang, Yan [1 ]
Wang, Jianbo [1 ,2 ]
机构：
[1] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 90期
关键词：
DELOCALIZED SINGLET VINYLCARBENES; RING-OPENING CYCLIZATION; CYCLOADDITION REACTIONS; STEREOSELECTIVE-SYNTHESIS; CATALYZED CARBOZINCATION; THERMAL-REACTIONS; X-(X; EFFICIENT; REARRANGEMENTS; CHEMISTRY;
D O I：
10.1039/c6cc06743c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines is reported. The reaction is a new demonstration of formal [3+2] cycloaddition triggered by ring-opening of cyclopropenes bearing electron-withdrawing substituents. The reaction provides a unique method for the construction of cyclopentene structures.
引用
收藏
页码：13285 / 13287
页数：3
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