Adsorption of Hydroquinone to Polycrystalline Gold Electrode and Its Effect on the Electrochemical Properties

被引：1
|
作者：
Naito, Kumi [1 ]
Maeda, Yuri [1 ]
Yasui, Takashi [1 ]
Takada, Kazutake [1 ]
Yuchi, Akio [1 ]
机构：
[1] Nagoya Inst Technol, Grad Sch Engn, Showa Ku, Nagoya, Aichi 4668555, Japan
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2017年 / 164卷 / 09期
关键词：
GLASSY-CARBON ELECTRODES; PLATINUM-ELECTRODES; TRANSFER KINETICS; EC-STM; ORIENTATION; VOLTAMMETRY; CATALYSIS; MOLECULES; QUINONES; SURFACES;
D O I：
10.1149/2.1641709jes
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Adsorption of hydroquinone (QH(2)) onto a polycrystalline gold electrode surface in an unbuffered aqueous solution was confirmed by cyclic voltammetry (CV) and time-of-flight secondary ion mass spectrometry. The adsorption appeared to inhibit direct electron transfer between QH(2) in the solution and the gold electrode. CV indicated that the surface coverage was ca. 9 x 10(-1)1 mol cm(-2). It was also demonstrated that when QH(2) was electrochemically oxidized, the adsorbed QH(2) likely desorbed from the gold surface. (C) 2017 The Electrochemical Society.
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页码：H670 / H674
页数：5
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