Fibre orientation effect on polypropylene/milled carbon fiber composites in the presence of carbon nanotubes or graphene as a secondary filler: Application on PEM fuel cell bipolar plate

被引:29
|
作者
Radzuan, Nabilah Afiqah Mohd [1 ]
Sulong, Abu Bakar [1 ,2 ]
Somalu, Mahendra Rao [1 ]
Abdullah, Ahmad Tajuddin [1 ]
Husaini, Teuku [1 ]
Rosli, Ros Emilia [1 ]
Majlan, Edy Herianto [1 ]
Rosli, Masli Irwan [3 ]
机构
[1] Univ Kebangsaan Malaysia, Fuel Cell Inst, Ukm Bangi 43600, Malaysia
[2] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Ctr Mat Engn & Smart Mfg, Mech Engn Programme, Ukm Bangi 43600, Malaysia
[3] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Dept Chem & Proc Engn, Bangi 43600, Selangor, Malaysia
关键词
Conductive polymer composite; Extrusion; Electrical conductivity; Mechanical properties; ELECTRICAL-CONDUCTIVITY; MECHANICAL-PROPERTIES; ELECTROLYTE; TEMPERATURE; PERFORMANCE; OXIDE; FABRICATION; EXTRUSION; DIAGNOSIS; CORROSION;
D O I
10.1016/j.ijhydene.2019.01.063
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Conductive polymer composite (CPC) materials are extensively used for the bipolar plate in Polymer Electrolyte Membrane Fuel Cells (PEMFCs). The produced CPC materials through the extrusion process strongly relate to electrical conductivity and mechanical properties. In this study, milled carbon fibre (MCF) reinforced polypropylene (PP) incorporating carbon nanotube (CNT), or graphene nanoplatelets (xGNP) are pre-mixed using the extrusion process to orientate the fibres before undergoing the compression moulding at 13.8 MPa and 200 degrees C for 15 min. The CNT composites exhibited the higher through-plane conductivity of 14.8 S/cm as compared to xGnP composites with 4.9 S/cm at 70 wt% of MCF. The flexural strength improved after being compressed to 99.6 MPa and 172.5 MPa for 70 wt% of CNT and xGNP, respectively. This reveals that the oriented fibres can boost the CPC performance. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:30618 / 30626
页数:9
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