Aqua{4,4′,6,6′-tetrafluoro-2,2′[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)

被引:5
|
作者
Kubono, Koji [1 ]
Tsuno, Yuki [1 ]
Tani, Keita [1 ]
Yokoi, Kunihiko [1 ]
机构
[1] Osaka Kyoiku Univ, Div Nat Sci, Osaka 5828582, Japan
关键词
CRYSTAL-STRUCTURES; COMPLEX;
D O I
10.1107/S1600536810040080
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C18H16F4N2O2)(H2O)], the Cu-II atom shows a distorted square-pyramidal coordination geometry with the N,N',O,O'-tetradentate piperazine-diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O-H center dot center dot center dot O and O-H center dot center dot center dot F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen bonds, giving infinite chains propagating along the a axis.
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页码:M1397 / U563
页数:14
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