Mg-doped Cu2O thin films with enhanced functional properties grown by magnetron sputtering under optimized pressure conditions

被引:3
|
作者
Sliti, Naama [1 ,2 ]
Fourneau, Emile [1 ]
Ratz, Thomas [1 ]
Touihri, Saad [2 ]
Ngoc Duy Nguyen [1 ]
机构
[1] Inst Phys, CESAM Q MAT Solid State Phys Interfaces & Nanostr, B5a,Allee Six Aout 19, B-4000 Liege, Belgium
[2] Univ Tunis, Ecole Natl Super Ingenieurs Tunis, 13 Ave Taha Hussein, Tunis 1008, Tunis, Tunisia
关键词
Magnesium; Cuprous oxide; Sputtering; Plasma pressure; p-type transparent conducting oxide; CUPROUS-OXIDE; ELECTRONIC-STRUCTURE; VAPOR-DEPOSITION; LOW-RESISTIVITY; ZNO FILMS; TRANSPARENT; TEMPERATURE; POWER;
D O I
10.1016/j.ceramint.2022.05.028
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cu2O appears as a promising material for synthesizing p-type transparent semiconducting oxides with low electrical resistivity and high optical transmittance. We report on an exhaustive study of magnesium-doped cuprous oxide layers deposited by radio frequency magnetron sputtering. We present the characterization of the structural and optoelectronic properties of Mg:Cu2O thin films deposited at room temperature with varied argon plasma pressure. As a result, we found that by adjusting the Ar plasma pressure, Mg-doped Cu2O layers with high crystallinity combined with optimal electrical and optical properties can be synthesized. Using a plasma pressure of 13 mTorr, we obtained a transparent p-type material with crystallite size of 15 nm, electrical resistivity of 10.2 Omega cm, and optical band gap of 2.55 eV.
引用
收藏
页码:23748 / 23754
页数:7
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