Deuterium Exchange Study for Hydrogenation of D5-1-Pentene (4,4,5,5,5) Over Conventional Cobalt Fischer-Tropsch Catalyst

被引：1
|
作者：
Gnanamani, Muthu Kumaran [1 ]
Shafer, Wilson D. [1 ]
Davis, Burtron H. [1 ]
机构：
[1] Univ Kentucky, Ctr Appl Energy Res, Lexington, KY 40511 USA
来源：
CATALYSIS LETTERS | 2012年 / 142卷 / 02期
关键词：
Deutero-1-pentene; Hydrogenation; Fischer-Tropsch; Cobalt; Deuterium exchange; HYDROCARBON SYNTHESIS; MECHANISM; OLEFINS; ACTIVATION; ETHYLENE; ETHANOL; TRACER; NICKEL;
D O I：
10.1007/s10562-011-0750-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogen-deuterium exchange reaction was performed for hydrogenation of D-5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer-Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N-2. The inhibition effects of CO and other FT products on H/D exchange of D-5-1-pentene and a pressure dependency effect on H/D exchange are observed.
引用
收藏
页码：190 / 194
页数：5
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