Noncovalent functional-group-arene interactions

被引：51
|
作者：
Motherwell, William B.
Moise, Joeelle
Aliev, Abil E.
Nic, Miloslav
Coles, Simon J.
Horton, Peter N.
Hursthouse, Michael B.
Chessari, Gianni
Hunter, Christopher A.
Vinter, Jeremy G.
机构：
[1] UCL, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England
[2] Univ Southampton, Sch Chem, EPSRC Natl Crystallog Serv, Southampton SO17 1BJ, Hants, England
[3] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
[4] Cresset Biomol Discovery, Letchworth SG6 4ET, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期
关键词：
conformation analysis; hydrogen bonds; NMR spectroscopy; noncovalent interactions; pi interactions;
D O I：
10.1002/anie.200701463
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Hanging in the balance: A series of dibenzobicyclo[3,2, 2]nonanes provides a delicate conformational balance for investigating weak interactions, such as O-H⋯π(Ar) π-hydrogen bonding (see scheme, red O) and solvent-solute interactions. The models are designed to probe the effectiveness of replacing a hydroxy group by fluorine or to compare the arene affinities of sulfur and oxygen. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7823 / 7826
页数：4
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