Transfer of organic groups to gold using organotin compounds

被引：18
|
作者：
Meyer, Nadine [1 ]
Sivanathan, Sivatharushan [1 ]
Mohr, Fabian [1 ]
机构：
[1] Berg Univ Wuppertal, Fachbereich Anorgan Chem C, D-42119 Wuppertal, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 06期
关键词：
Transmetallation; Organotin compounds; Arylgold(I) compounds; X-ray structure; TETRAORGANOTIN COMPOUNDS; BOND FORMATION; TIN COMPOUNDS; ARYL LIGANDS; COMPLEXES; PRECURSORS; REAGENTS;
D O I：
10.1016/j.jorganchem.2010.10.060
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
PhSnMe3 undergoes transmetallation with [AuCl(EPh3)] (E P, As) in refluxing toluene forming [AuPh(EPh3)] and Me3SnCl. The analogous Bu-n derivative does not transmetallate, even under forcing conditions. Similarly, 1-(trimethylstannyl) naphthalene and 1-(trimethylstannyl)-8-iodonaphthalene react with [AuCl(PPh3)] to give good yields of the corresponding naphthylgold(I) complexes which were spectroscopically and structurally characterised. (C) 2010 Elsevier B.V. All rights reserved.
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页码：1244 / 1247
页数：4
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