Molecular Magnet Based on a Thiocyanato-Bridged Heterobimetallic Complex: Synthesis and Magnetic Properties

被引：0
|
作者：
Bi, Jian-Hong [1 ]
Bi, Wen-Tao [2 ]
Hu, Nai-Liang [3 ]
机构：
[1] Hefei Normal Univ, Dept Chem & Chem Engn, Hefei, Peoples R China
[2] SINOPEC, Inst Petr Explorat & Dev, Hefei Training & Anal Ctr, Hefei 230022, Peoples R China
[3] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 02期
关键词：
Heterobimetallic complex; Tetraza macrocycle; Self-assemble; Synthesis; Magnetic property;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One new self-assembled heterobimetallic complex with the composition CuL-Co(SCN)(4) (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been prepared and characterized by IR spectra and elemental analysis. The molecular magnetic properties of the complex were characterized by magnetic susceptibility and presents a antiferromagnetic interaction between the tetraaza macrocycle Cu(II) ions and Co(SCN)(4)(2-) through the thiocyanato-bridged in the complex.
引用
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页码：941 / 942
页数：2
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