Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes

被引：7
|
作者：
Tsai, MS [1 ]
Rao, UN [1 ]
Hsueh, PY [1 ]
Yeh, MCP [1 ]
机构：
[1] Natl Taiwan Normal Univ, Dept Chem, Taipei 117, Taiwan
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 02期
关键词：
D O I：
10.1021/om000719f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.
引用
收藏
页码：289 / 295
页数：7
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