Metal complexes of biologically important ligands .87. alpha-Amino carboxylate complexes of palladium(II), iridium(III) and ruthenium(II) from chloro-bridged ortho-metallated metal compounds and [(OC)(3)Ru(Cl)(mu-Cl)](2)

被引：70

作者：

Urban, R ^{[1
]}

Kramer, R ^{[1
]}

Mihan, S ^{[1
]}

Polborn, K ^{[1
]}

Wagner, B ^{[1
]}

Beck, W ^{[1
]}

机构：

[1] UNIV MUNICH, INST ANORGAN CHEM, D-80333 MUNICH, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 517卷 / 1-2期

关键词：

palladium; iridium; ruthenium; biologically-important ligands; alpha-amino carboxylates;

D O I：

10.1016/0022-328X(96)06166-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chloro-bridged ortho-metallated compounds [(L)Pd(mu-Cl)](2) (HL=2-benzylpyridine, 2-phenylpyridine, azobenzene) and [(L)(2)Ir(mu-Cl)](2) (LH=2-phenylpyridine) react with alpha-amino carboxylates to give the N,O-chelate complexes (L)Pd-NH2C(H)(R)CO2 and (L)(2)Ir-NH2C(H)(R)CO2. The chloro-bridged carbonyl complex [(OC)(3)Ru(Cl)(mu-Cl)](2) and prolinate afford the N,O-chelate (Cl)(OC)(3)Ru(prolinate). From the osmium complex [(OC)(3)Os(Cl)(p-Cl)](2) and N,N-dimethylglycine methylester the ionic compound [HN(Me(2))CH(2)CO(2)Et](+)(Os(CO)(3)Cl-3)(-) (25) was obtained. The structures of [2-(2-pyridylmethyl)phenyl-C-1,N]Pd(prolinate)], [(2-pyridylphenyl-C-1,N)(2)Ir(prolinate)] and of 25 were determined by X-ray diffraction.

引用

页码：191 / 200

页数：10

共 19 条

[1] Metal complexes of biologically important ligands, LXXXVII a-Amino carboxylate complexes of palladium(II), iridium(III) and ruthenium(II)from chloro-bridged ortho-metallated metal compounds and [(OC)3Ru(CI)(ae-C1)]2
Urban, R.
Kraemer, R.
Mihan, S.
Polborn, K.
Journal of Organometallic Chemistry, 517 (1-2):
[2] Metal complexes of biologically important ligands .85. Coordination compounds of cobalt(III), iridium(III), ruthenium(II) and palladium(II) with isoxazole- and isoxazoline-3-carboxylates
Lampeka, R
Mihan, S
Beck, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (04): : 581 - 587
[3] METAL-COMPLEXES WITH BIOLOGICALLY IMPORTANT LIGANDS .65. CHIRAL HALF-SANDWICH COMPLEXES OF COBALT(III), RHODIUM(III), IRIDIUM(III), AND RUTHENIUM(II) WITH ALPHA-AMINO AMIDE, GLYCINENITRILE, AND PEPTIDE ESTER LIGANDS
KRAMER, R
MAURUS, M
BERGS, R
POLBORN, K
SUNKEL, K
WAGNER, B
BECK, W
CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (09): : 1969 - 1980
[4] Metal complexes of biologically important ligands, CXL [1]. Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids
Koch, Daniela
Beck, Wolfgang
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2001, 56 (12): : 1271 - 1280
[5] Metal complexes of biologically important ligands, 130.: Chiral chloro-bridged η6-phenylglycine ruthenium(II) complexes formed by dehydrogenation of (R)-2,5-dihydrophenylglycine
Dialer, H
Mayer, P
Polborn, K
Beck, W
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (04) : 1051 - 1055
[6] METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .53. CHIRAL HALF-SANDWICH COMPLEXES OF RHODIUM(III), IRIDIUM(III), IRIDIUM(I), AND RUTHENIUM(II) WITH ALPHA-AMINO-ACID ANIONS
KRAMER, R
POLBORN, K
WANJEK, H
ZAHN, I
BECK, W
CHEMISCHE BERICHTE, 1990, 123 (04) : 767 - 778
[7] METAL-COMPLEXES WITH BIOLOGICALLY IMPORTANT LIGANDS .73. ORGANOMETALLIC COMPOUNDS OF PALLADIUM(II), PLATINUM(II), RHODIUM(III) AND IRIDIUM(III) WITH N-6-DEOXY-GALACTOPYRANOSYL-ALPHA-AMINO ACIDS
ZHOU, YL
WAGNER, B
POLBORN, K
SUNKEL, K
BECK, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (09): : 1193 - 1202
[8] METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS .50. PALLADIUM(II), PLATINUM(II) AND COPPER(II) COMPLEXES OF ALPHA-AMINO ACID-N-GLYCOSIDES AND OF FRUCTOSE-AMINO ACIDS (AMADORI-COMPOUNDS)
CHEN, JT
PILL, T
BECK, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (04): : 459 - 464
[9] Metal complexas of biologically important ligands.: CXL.: Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids
Koch, D
Beck, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2001, 56 (12): : 1271 - 1280
[10] Metal complexes with biologically important ligands, CIX -: Organometallic compounds of platinum(II), ruthenium(II), rhodium(III), and iridium(III) with oxocarbonyl-N-protected α-amino acids and L-methionylglycinate
Prem, M
Polborn, K
Beck, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1998, 53 (12): : 1501 - 1505

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