Achieving the photon up-conversion thermodynamic yield upper limit by sensitized triplet-triplet annihilation

被引：138
|
作者：
Hoseinkhani, S. [1 ]
Tubino, R. [1 ]
Meinardi, F. [1 ]
Monguzzi, A. [1 ]
机构：
[1] Univ Milano Bicocca, Dipartimento Sci Mat, I-20125 Milan, Italy
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2015年 / 17卷 / 06期
关键词：
SOLAR-CELLS; FLUORESCENCE; PERYLENE; LIGHT; FUSION;
D O I：
10.1039/c4cp03936j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Triplet-triplet annihilation (TTA) based up-conversion is a promising strategy for light harvesting the low-energy tail of the solar spectrum with photovoltaic technologies. Here, we present a bi-component system for photon managing via TTA that allows bypassing the classical statistic limit of 2/5 in the singlet generation, achieving a near unitary conversion efficiency. This result is obtained because of the peculiar relative position of the triplet and singlet energy levels of perylene, used as up-converter and emitter. The system shows a record red-to-blue external up-conversion yield of similar to 10% under an irradiance of 1 sun.
引用
收藏
页码：4020 / 4024
页数：5
相关论文
共 50 条
  • [1] Triplet-triplet annihilation up-conversion
    Schmidt, Timothy W.
    Tayebjee, Murad J. Y.
    RSC Energy and Environment Series, 2014, 2014-January (11): : 489 - 505
  • [2] Towards the IR Limit of the Triplet-Triplet Annihilation-Supported Up-Conversion: Tetraanthraporphyrin
    Yakutkin, Vladimir
    Aleshchenkov, Sergei
    Chernov, Sergei
    Miteva, Tzenka
    Nelles, Gabriele
    Cheprakov, Andrei
    Baluschev, Stanislav
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (32) : 9846 - 9850
  • [3] Triplet-triplet annihilation photon up-conversion: Accessing triplet excited states with minimum energy loss
    Hussain, Mushraf
    Razi, Syed S.
    Tao, Tao
    Hartl, Frantisek
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2023, 56
  • [4] Photon upconversion based on sensitized triplet-triplet annihilation
    Singh-Rachford, Tanya N.
    Castellano, Felix N.
    COORDINATION CHEMISTRY REVIEWS, 2010, 254 (21-22) : 2560 - 2573
  • [5] Triplet-triplet annihilation based photon up-conversion in hybrid molecule-semiconductor nanocrystal systems
    Ronchi, Alessandra
    Brazzo, Paolo
    Sassi, Mauro
    Beverina, Luca
    Pedrini, Jacopo
    Meinardi, Francesco
    Monguzzi, Angelo
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (23) : 12353 - 12359
  • [6] On the Quantum Yield of Photon Upconversion via Triplet-Triplet Annihilation
    Zhou, Yan
    Castellano, Felix N.
    Schmidt, Timothy W.
    Hanson, Kenneth
    ACS ENERGY LETTERS, 2020, 5 (07): : 2322 - 2326
  • [7] BODIPY-Perylene Charge Transfer Compounds; Sensitizers for Triplet-Triplet Annihilation Up-conversion
    Arellano-Reyes, Ruben Arturo
    Prabhakaran, Amrutha
    Sia, Rengel Cane E.
    Guthmuller, Julien
    Jha, Keshav Kumar
    Yang, Tingxiang
    Dietzek-Ivansic, Benjamin
    McKee, Vickie
    Keyes, Tia E.
    CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (24)
  • [8] Quantum Dot-Sensitized Triplet-Triplet Annihilation Photon Upconversion for Solar Energy Conversion and beyond
    Huang, Zhiyuan
    Tung, Chen-Ho
    Wu, Li-Zhu
    ACCOUNTS OF MATERIALS RESEARCH, 2024, 5 (02): : 136 - 145
  • [9] Metallophthalocyanines as triplet sensitizers for highly efficient photon upconversion based on sensitized triplet-triplet annihilation
    J. L. Han
    J. You
    H. Yonemura
    S. Yamada
    S. R. Wang
    X. G. Li
    Photochemical & Photobiological Sciences, 2016, 15 : 1039 - 1045
  • [10] Metallophthalocyanines as triplet sensitizers for highly efficient photon upconversion based on sensitized triplet-triplet annihilation
    Han, J. L.
    You, J.
    Yonemura, H.
    Yamada, S.
    Wang, S. R.
    Li, X. G.
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2016, 15 (08) : 1039 - 1045
12345