Sulfonated polyethylene glycol (PEG-OSO3H) as a polymer supported biodegradable and recyclable catalyst in green organic synthesis: recent advances

被引：38

作者：

Vekariya, Rajesh H. ^{[1
]}

Patel, Hitesh D. ^{[1
]}

机构：

[1] Gujarat Univ, Sch Sci, Dept Chem, Ahmadabad 380009, Gujarat, India

来源：

RSC ADVANCES | 2015年 / 5卷 / 61期

关键词：

SOLVENT-FREE SYNTHESIS; EFFICIENT HETEROGENEOUS CATALYST; CROSS-ALDOL CONDENSATION; ACID-MODIFIED PEG-6000; MANNICH-TYPE REACTION; SILICA SULFURIC-ACID; HIGHLY EFFICIENT; BECKMANN REARRANGEMENT; CHEMOSELECTIVE SYNTHESIS; REUSABLE CATALYST;

D O I：

10.1039/c5ra06532a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The objective of this review is to summarize some of the recent advances in a sulfuric acid-modified polyethylene glycol 6000 (PEG-OSO3H) as a stable, recyclable and bio-degradable polymeric catalyst in organic synthesis. PEG-OSO3H is a highly efficient and eco-friendly catalyst, which catalyzed various organic reactions and could be recovered and reused several times without significant loss of its activity. In this review, preparation and application of PEG-OSO3H in organic synthesis are investigated.

引用

页码：49006 / 49030

页数：25

共 24 条

[1] PEG-OSO3H as an efficient and recyclable catalyst for the synthesis of β-amino carbonyl compounds via the Mannich reaction in PEG-H2O
Wang, Xi Cun
Zhang, Li Jia
Zhang, Zhang
Quan, Zheng Jun
CHINESE CHEMICAL LETTERS, 2012, 23 (04) : 423 - 426
[2] PEG-OSO3H as an efficient and recyclable catalyst for the synthesis of β-amino carbonyl compounds via the Mannich reaction in PEG-H2O
Xi Cun Wang~*
ChineseChemicalLetters, 2012, 23 (04) : 423 - 426
[3] Dual role of the polymer supported catalyst PEG-OSO3H in aqueous reaction medium: synthesis of highly substituted structurally diversified coumarin and uracil fused spirooxindoles
Paul, Sanjay
Das, Asish R.
TETRAHEDRON LETTERS, 2013, 54 (09) : 1149 - 1154
[4] PEG-OSO3H AS AN EFFICIENT CATALYST IN THE SYNTHESIS OF N3-FUNCTIONALIZED 3.4-DIHYDROPYRIMIDINONE AND QUINAZOLINONE DERIVATIVES
Yang, Liang-Jie
Luo, Jin-Ge
Wang, Xi-Cun
HETEROCYCLES, 2017, 94 (06) : 1027 - 1039
[5] MNP-cellulose-OSO3H as an efficient and biodegradable heterogeneous catalyst for green synthesis of trisubstituted imidazoles
Saeedi, Shaghayegh
Rahmati, Abbas
RSC ADVANCES, 2022, 12 (19) : 11740 - 11749
[6] Facile synthesis of ninhydrin and isatin based hydrazones in water using PEG-OSO3H as a highly efficient and homogeneous polymeric acid-surfactant combined catalyst
Debnath, Kamalesh
Pathak, Sudipta
Pramanik, Animesh
TETRAHEDRON LETTERS, 2013, 54 (31) : 4110 - 4115
[7] Insights into microwave assisted synthesis of spiro-chromeno[2,3-d] pyrimidines using PEG-OSO3H catalyst: DFT study and their antiproliferative activity
Patel, Subham G.
Patel, Paras J.
Upadhyay, Dipti B.
Puerta, Adrian
Malik, Apoorva
Kandukuri, Nagesh K.
Sharma, Rakesh K.
Padron, Jose M.
Patel, Hitendra M.
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1292
[8] Sulfuric acid-modified PEG-6000 (PEG-OSO3H): a biodegradable, reusable solid acid catalyst for highly efficient and eco-friendly synthesis of novel bis-Knoevenagel products under solvent-free conditions
Siddiqui, Zeba N.
Khan, Tabassum
TETRAHEDRON LETTERS, 2013, 54 (29) : 3759 - 3764
[9] Sulfuric acid-modified PEG-6000 (PEG-OSO3H): an efficient Bronsted acid-surfactant combined catalyst for the one-pot three component synthesis of α-aminonitriles in water
Shekouhy, Mohsen
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (05) : 1010 - 1020
[10] Sulfuric acid-modified PEG-6000 (PEG-OSO3H): an efficient, bio-degradable and reusable polymeric catalyst for the solvent-free synthesis of poly-substituted quinolines under microwave irradiation
Hasaninejad, Alireza
Zare, Abdolkarim
Shekouhy, Mohsen
Ameri-Rad, Javad
GREEN CHEMISTRY, 2011, 13 (04) : 958 - 964

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