Selective oxidation of cycloalkanes over iron-substituted hexagonal mesoporous aluminophosphate molecular sieves

被引：9

作者：

Mohapatra, SK ^{[1
]}

Selvam, P ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 02期

关键词：

D O I：

10.1246/cl.2004.198

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron-substituted hexagonal mesoposours aluminiphosphate (FeHMA) molecular sieves oxidize cycloalkanes into cycloalkanols and cycloalkanones with excellent yield in the presence of molecular oxygen or air under mild reaction conditions. The catalyst showed higher activity as compared to mesoporous FeMCM-41 as well as microporous FeS-1 and FeAPO-5 molecular sieves, and that FeHMA can be recycled without much loss in activity.

引用

页码：198 / 199

页数：2

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