Preparation and Crystal Structure of a Two-Dimensional Cadmium(II) Coordination Polymer Containing Bismuthiol(I) as a Bridging Ligand

被引：0

作者：

Wang Wen-Xiang ^{[1
]}

Zhao Hong ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 06期

关键词：

cadmium complex; hydrothermal reaction; crystal structure; fluorescence; MOLECULAR-STRUCTURE; COMPLEXES; SPECTRA;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of CdCl2 with 1,3,4-thiadiazole-2,5-dithiol affords one 2D network cadmium(II) coordination polymer, [Cd(5-thioxo-4,5-dihydro-1,3,4-thiadiazole-2-thiolate)(2)](n). The structure was determined by single crystal X-ray diffraction, the crystal belongs to orthorhombic system with space group Pbcn, and a=1.281 6(2) nm, b=1.162 1(2) nm, c=0.78406(16) nm, V=1.167 7(4) nm(3), Z=4. Its fluorescence was measured. CCDC: 689817.

引用

页码：1109 / 1112

页数：4

共 22 条

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