Electrochemical codeposition of Pt/graphene catalyst for improved methanol oxidation

被引:36
|
作者
Woo, Seunghee [1 ]
Lee, Jaeyoung [2 ]
Park, Seung-Keun [3 ]
Kim, Hasuck [4 ]
Chung, Taek Dong [1 ]
Piao, Yuanzhe [3 ,5 ]
机构
[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
[2] Gwangju Inst Sci & Technol, Ertl Ctr Electrochem & Catalysis, Sch Environm Sci & Engn, Kwangju 500712, South Korea
[3] Seoul Natl Univ, Grad Sch Convergence Sci & Technol, Seoul 151742, South Korea
[4] Daegu Gyeongbuk Inst Sci & Technol, Dept Energy Syst Engn, Taegu 711874, South Korea
[5] Adv Inst Convergence Technol, Suwon 443270, South Korea
基金
新加坡国家研究基金会;
关键词
Pulsed galvanostatic electrodeposition; Platinum; Graphene; Electrocatalyst; Methanol oxidation; REDUCED GRAPHENE OXIDE; OXYGEN-REDUCTION; PULSE ELECTRODEPOSITION; SUPPORTED PLATINUM; CATHODE CATALYST; CARBON SUPPORTS; PERFORMANCE; NANOPARTICLES; ELECTROCATALYSTS; FABRICATION;
D O I
10.1016/j.cap.2014.12.022
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Pt/graphene electrocatalyst was uniformly deposited on a glassy carbon substrate using a pulsed galvanostatic electrodeposition method, which facilitated the simultaneous electrochemical reduction of graphene oxide and formation of Pt nanoparticles. Compared to the commercial carbon-supported Pt electrocatalyst, the electrochemically reduced Pt/graphene (Pt/ERG) catalyst exhibited improved electrocatalytic activity for methanol oxidation due to the synergistic effects of an increase in the number of catalytic reaction sites and an enhancement of the charge transfer rate. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:219 / 225
页数:7
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