Multifunctional perovskite oxide for efficient solar-driven evaporation and energy-saving regeneration

被引:37
|
作者
Wang, Yuchao [1 ,4 ]
Wang, Canzhu [1 ,2 ]
Liang, Wenyuan [1 ]
Song, Xiangju [1 ,3 ]
Zhang, Yajing [1 ,2 ]
Huang, Minghua [2 ]
Jiang, Heqing [1 ,4 ]
机构
[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Funct Membrane Mat & Membrane Tec, Qingdao 266101, Peoples R China
[2] Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[4] Chinese Acad Sci, Ctr Ocean Megasci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
基金
中国国家自然科学基金;
关键词
Solar-driven evaporation; Multifunctional perovskite; Catalytic combustion; Energy-saving regeneration; Salt rejection; WATER EVAPORATION; MEMBRANE REACTOR; GENERATION; STILL;
D O I
10.1016/j.nanoen.2020.104538
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photothermal materials, which can realize the light-to-heat conversion, are the key factor to fast solar-driven evaporation for fresh water generation in desalination. In practical application, photothermal materials often meet the biological or organic contaminants, causing performance degradation or even invalidation. Pyrolysis is an ideal approach to contaminants decomposition for some thermostable materials, but still suffers high energy consumption. Here, a multi-functional cobalt-containing perovskite, La0.7Sr0.3CoO3, is developed for high-efficiency solar-driven evaporation and energy-saving regeneration in view of the good photothermal performance and activity in catalytic combustion. La0.7Sr0.3CoO3 slice with rationally designed surface and microstructure accelerates the evaporation up to 1.67 kg m(-2) h(-1), about 420% of natural water evaporation rate under 1.0-sun illumination. More importantly, La0.7Sr0.3CoO3 slice can catalyze the thermal decomposition of biological/organic contaminants like alga at a relatively lower temperature, meaning a lower energy consumption. Additionally, because of the superhydrophilic surface and porous structure for high accessibility of seawater, La0.7Sr0.3CoO3 slice can realize long-term salt rejection and ensure a stable performance on seawater evaporation which is meaningful in the practical solar-driven desalination.
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页数:8
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