CsB3O4(OH)2: a new deep-ultraviolet birefringent crystal with [B3O4(OH)2] anionic group

被引：5
|
作者：
Wang, Xinyue [1 ]
Zhang, Bingbing [1 ]
Yang, Daqing [1 ]
Wang, Ying [1 ]
机构：
[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
来源：
DALTON TRANSACTIONS | 2022年 / 51卷 / 37期
基金：
中国国家自然科学基金;
关键词：
NONLINEAR-OPTICAL CRYSTAL; ALKALINE-EARTH; BORATE; GROWTH; EDGE;
D O I：
10.1039/d2dt02573f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new cesium hydroxyborate CsB3O4(OH)(2), was designed and synthesized by a hydrothermal method. Remarkably, CsB3O4(OH)(2) presents novel [B3O4(OH)(2)](infinity) chains formed by [B3O4(OH)(2)] fundamental building blocks (FBBs). The report of less common [B3O4(OH)(2)] FBBs and [B3O4(OH)(2)](infinity) chains in CsB3O4(OH)(2) enriches the structural diversity of hydroxyborates. In addition, CsB3O4(OH)(2) has a wide transparent window in the DUV spectral range and a large birefringence.
引用
收藏
页码：14059 / 14063
页数：5
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