A novel nitrite sensor based on graphene/polypyrrole/chitosan nanocomposite modified glassy carbon electrode

被引:127
|
作者
Ye, Daixin [1 ]
Luo, Liqiang [1 ]
Ding, Yaping [1 ]
Chen, Qiang [1 ]
Liu, Xiao [1 ]
机构
[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
基金
中国国家自然科学基金;
关键词
ONE-STEP ELECTRODEPOSITION; SENSITIVE DETERMINATION; ELECTROCHEMICAL DETERMINATION; ELECTROCATALYTIC REDUCTION; AMPEROMETRIC DETECTION; MESOPOROUS CARBON; CYTOCHROME-C; POLYPYRROLE; OXIDATION; FILM;
D O I
10.1039/c1an15486a
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel nitrite sensor was fabricated based on a graphene/polypyrrole/chitosan nanocomposite film modified glassy carbon electrode. The nanocomposite film was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. The electron transfer behaviour of the modified electrodes was investigated in [Fe(CN)(6)](3-)/(4-) redox probe using cyclic voltammetry and electrochemical impedance spectroscopy. Differential pulse voltammetry and amperometry were used to study the electrochemical properties of the proposed sensor. Under optimum conditions, the sensor exhibited good reproducibility and stability for nitrite determination. Linear response was obtained in the range of 0.5-722 mu M with a detection limit of 0.1 mu M (S/N = 3) for nitrite determination.
引用
收藏
页码:4563 / 4569
页数:7
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