B(C6F5)3-catalyzed metal-free hydrogenation of naphthylamines

被引：19
|
作者：
Li, Gen [1 ]
Liu, Yongbing [1 ]
Du, Haifeng [1 ]
机构：
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 10期
基金：
美国国家科学基金会;
关键词：
FRUSTRATED LEWIS PAIRS; FREE ASYMMETRIC HYDROGENATION; FREE CATALYTIC-HYDROGENATION; ENANTIOSELECTIVE HYDROGENATION; POLYCYCLIC ARENES; BH-BORANES; REDUCTION; BIS(PENTAFLUOROPHENYL)BORANE; ANTHRACENE; MECHANISM;
D O I：
10.1039/c5ob00009b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A catalytic metal-free hydrogenation of naphthylamines using B(C6F5)(3) as a catalyst was successfully achieved under mild conditions for the first time to furnish a variety of tetrahydronaphthylamines in 88-99% yields.
引用
收藏
页码：2875 / 2878
页数：4
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