Self-assembled hybrid solid of luminescent Ru(II)/Cu(II) polypyridyl metal-organic framework

被引：4
|
作者：
Polapally, Mamatha [1 ]
Chen, Banghao [2 ]
Kinyon, Jared [2 ]
Yan, Bangbo [1 ]
Dalal, Naresh [2 ]
机构：
[1] Western Kentucky Univ, Dept Chem, Bowling Green, KY 42101 USA
[2] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 84卷
关键词：
Ruthenium; Copper; Ferromagnetic; Polypyridyl; Metal-organic framework; RUTHENIUM(II) METALLOLIGAND; ENERGY-TRANSFER; PHOTOCATALYSIS; COMPLEXES; STORAGE;
D O I：
10.1016/j.inoche.2017.07.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new ruthenium(II) polypyridyl based metal-organic framework, [Ru(H(2)bpc)(Cu(bpc)(Hbpc)(2)(H2O))]center dot 5H(2)O (H(2)bpc = 2,2'-bipyridine-4,4'-dicarboxylic acid) has been hydro(solvo)thermally synthesized from RuCl3, CuSO4, and H(2)bpc, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV-vis spectroscopy. The compound contains 1D zigzag chains of [Ru(H(2)bpc)(Hbpc)(bpc)](-) complexes ions bridged by [Cu(Hbpc)(H2O)](+) ions. The compound shows fluoresce at 610 nm. Magnetic data at temperatures above 100 K follows the Curie-Weiss rule with theta = 34 K and C = 0.43 emu.mol(-1).K indicating the presence of ferromagnetic interactions between the copper ions. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：93 / 95
页数：3
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