Iridium(IV) extraction with petroleum sulfoxides from hydrochloric acid solutions

被引:2
|
作者
Afzaletdinova, N. G. [1 ]
Murinov, Yu I. [1 ]
机构
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia
关键词
COMPLEXES;
D O I
10.1134/S0036023610080292
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Iridium(IV) extraction with petroleum sulfoxides (PSO) from hydrochloric acid solutions is studied. Optimum conditions of extraction are chosen. It is shown that in the investigated extraction systems for a phase contact time of 30 min, iridium(IV) is extracted by the ion-associative mechanism. Electronic, (1)H NMR, and IR-spectroscopy, and elemental analysis are used to establish the structure of the extracted compound.
引用
收藏
页码:1312 / 1315
页数:4
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