Ambiphilic reactivity of 2,4-dinitrobenzyl p-tolyl sulfone carbanion

被引：0
|
作者：
Makosza, M [1 ]
Mathur, SN [1 ]
Bialecki, M [1 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
来源：
POLISH JOURNAL OF CHEMISTRY | 1998年 / 72卷 / 07期
关键词：
alkylation; carbanions; vicarious nucleophilic substitution of hydrogen;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbanions of 2,4-dinitrobenzyl p-tolyl sulfone (3a) and 5-chloro-2,4-dinitrobenzyl p-tolyl sulfone (3b) behave as ambiphilic reagents able to react with nucleophiles and electrophiles. The reaction course depends on the type of the reagent and of the base used in the reaction.
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页码：1198 / 1201
页数：4
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