Synthesis and Characterization of Allyl Terpene Maleate Monomer

被引:1
|
作者
Gu, Yan [1 ,2 ]
Hummel, Matthew [2 ]
Muthukumarappan, Kasiviswanathan [2 ]
Zhao, Zhendong [1 ]
Gu, Zhengrong [2 ]
机构
[1] Natl Forestry & Grassland Adm, Key Lab Biomass Energy & Mat, Key Lab Chem Engn Forest Prod, Natl Engn Lab Biomass Chem Utilizat,CAF,Inst Chem, Nanjing 210042, Jiangsu, Peoples R China
[2] South Dakota State Univ, Agr & Biosyst Engn Dept, Brookings, SD 57006 USA
基金
美国食品与农业研究所;
关键词
POLYESTERS;
D O I
10.1038/s41598-019-55356-8
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation.
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页数:11
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