Synthesis and photochemical properties of phenoxy derivatives of anthra[2,3-b]furan-5,10-dione

被引：3
|
作者：
Shchekotikhin, A. E. [1 ,2 ]
Shevtsova, E. K. [1 ]
Luzikov, Yu. N. [2 ]
Barachevskii, V. A. [3 ]
Traven, V. F. [1 ]
机构：
[1] Mendeleev Russian Univ Chem Technol, Moscow 125047, Russia
[2] Gauze Res Inst Antibiot, Moscow, Russia
[3] Russian Acad Sci, Photochem Ctr, Moscow, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 44卷 / 06期
关键词：
Phenoxy; Phenoxy Group; Light Yellow Crystal; Quinizarin; Photoinduced Form;
D O I：
10.1134/S1070428008060134
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nucleophilic replacement of the hydroxy groups in ethyl 4,11-dihydroxy-2-methyl-5,10-dioxo-5,10-dihydroanthra[2,3-b]furan-3-carboxylate by chlorine upon treatment with phosphorus acid chlorides gave the corresponding 4(11)-chloro derivatives which were converted into photochromic ethyl 4(11)-phenoxy-2-methyl-5,10-dioxo-5,10-dihydroanthra[2,3-b]furan-3-carboxylates. Photoinduced decomposition of the latter leads to the formation of phenol and fluorescent hydroxyanthra[2,3-b]furandiones.
引用
收藏
页码：855 / 862
页数：8
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