Thermodynamics and structure of hydrogen, methane, argon, oxygen and carbon dioxide adsorbed on single wall carbon nanotube bundles

被引:13
|
作者
Bienfait, M. [1 ]
Zeppenfeld, P. [2 ]
Dupont-Pavlovsky, N. [3 ]
Muris, M. [1 ,6 ]
Johnson, M. [4 ]
Wilson, T. [5 ]
De Pies, M. [5 ]
Vilches, O. E. [5 ]
机构
[1] Fac Luminy, CNRS CRMC2, F-13288 Marseille 9, France
[2] Johannes Kepler Univ Linz, Inst Expt Phys, A-4040 Linz, Austria
[3] Univ H Poincare, LCSM, F-54506 Vandoeuvre Les Nancy, France
[4] Inst Laue Langevin, F-38042 Grenoble 9, France
[5] Univ Washington, Dept Phys, Seattle, WA 98195 USA
[6] Makassar State Univ, Dept Phys, Makassar 90222, Indonesia
基金
美国国家科学基金会;
关键词
Physical adsorption; Carbon nanotubes; Adsorption isotherms; Neutron scattering; Surface structure;
D O I
10.1016/j.physb.2004.03.130
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Isosteric heat of adsorption and neutron diffraction measurements of hydrogen, methane, argon, oxygen and carbon dioxide adsorbed on single wall carbon nanotube bundles show that all adsorbates, except CO(2), condense first on high-energy binding sites like the grooves and the widest interstitial channels and then on the outer rounded surface of the bundles. As for CO(2), only one set of adsorption sites is observed, which is attributed to the grooves and/or the interstitial channels. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:E423 / E426
页数:4
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