Investigation of Promising Air Electrode for Realizing Ultimate Lithium Oxygen Battery

被引:56
|
作者
Luo, Wen-Bin [1 ]
Gao, Xuan-Wen [2 ]
Chou, Shu-Lei [1 ]
Kang, Yong-Mook [2 ]
Wang, Jia-Zhao [1 ]
Liu, Hua-Kun [1 ]
Dou, Shi-Xue [1 ]
机构
[1] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
[2] Dongguk Univ Seoul, Dept Energy & Mat Engn, Seoul 100715, South Korea
关键词
air electrode; electrocatalysts; lithium oxygen batteries; oxygen reduction reaction; oxygen evolution reaction; HIGHLY EFFICIENT ELECTROCATALYST; CYCLING LI-O-2 BATTERIES; CARBON-FREE; BIFUNCTIONAL CATALYST; REDOX MEDIATOR; LIOH FORMATION; BINDER-FREE; CATHODE; NANOTUBES; REDUCTION;
D O I
10.1002/aenm.201700234
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The non-aqueous lithium oxygen battery has been considered as one of the most promising energy storage systems owing to its potentially high energy density, exceeding that of any other existing storage system for storing sustainable and clean energy. The success of Li-O-2 batteries could efficiently reduce greenhouse gas emissions and the consumption of non-renewable fossil fuels. How to achieve high round-trip efficiency, high capacity, and satisfactory cycling performance, however, is still a great challenge for the lithium oxygen battery. Thus, this report will point out what factors will affect the electrochemical performance and will aim to describe how to increase the electrochemical performance by air electrode optimization. Based on recent achievements, several approaches to solving this problem, such as synthesizing electrocatalysts with high catalytic activity and designing appropriate air electrode structures, are described in details. Also, recent progress associated with novel air electrode designs and understanding the reaction process is discussed.
引用
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页数:13
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