Cycloaddition reactions of 2H-benzo[b]thiete and conjugated cyclic dienes

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作者
Groschl, D
Meier, H
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O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2H-Benzo[b]thiete 1 reacts with cyclopentadiene 3 in consecutive [8 pi + 2 pi]cycloadditions yielding the condensed heterocycles 6-8. Tetracyclone 9 on the other hand gives only the monoadduct 10. An [8 pi + 8 pi]cycloaddition can be observed for 1 and diphenylisobenzofuran 11. The related phi system 13 shows again consecutive [47 pi + 27 pi]processes (1 + 13 --> 14, 15).
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页码:1727 / 1729
页数:3
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