Determination of the kinetic and thermodynamic parameters of adsorption processes by a volume step thermal method

被引：3
|
作者：
Abdallah, K [1 ]
Bourdin, V [1 ]
Grenier, P [1 ]
Malka-Edery, A [1 ]
Sun, LM [1 ]
机构：
[1] CNRS, LIMSI, F-91403 Orsay, France
来源：
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2001年 / 7卷 / 01期
关键词：
diffusion; kinetics; adsorption heat; measurement method; NaX; carbon dioxide;
D O I：
10.1023/A:1011204415436
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A volume step method measuring the pressure and the adsorbent temperature of an adsorbent-adsorbate system has been developped. It is shown that this method allows the determination of all the relevant parameters of an adsorption process, kinetic as well as thermodynamic in case of Linear Driving Force mass transfer. The method for determining the parameters can be extended to the case of diffusive mass transfer if the mass transfer kinetics is faster than the heat transfer kinetics. An example is given, showing the determination of the diffusion coefficient of carbon dioxide in NaX zeolite pellets and the change of the diffusion coefficient and of the isosteric heat of adsorption when the adsorbent is not fully dehydrated.
引用
收藏
页码：5 / 16
页数：12
相关论文
共 50 条
  • [1] Determination of the Kinetic and Thermodynamic Parameters of Adsorption Processes by a Volume Step Thermal Method
    K. Abdallah
    V. Bourdin
    Ph. Grenier
    A. Malka-Edery
    L.M. Sun
    Adsorption, 2001, 7 : 5 - 16
  • [2] Evaluation of the ASTM E 698 method for determination of kinetic parameters of thermal decomposition processes
    Stolarek, Pawel
    Ledakowicz, Stanislaw
    2003, Ars Polona (24):
  • [3] Evaluation of the ASTM E 698 method for determination of kinetic parameters of thermal decomposition processes
    Stolarek, P
    Ledakowicz, S
    INZYNIERIA CHEMICZNA I PROCESOWA, 2003, 24 (04): : 701 - 715
  • [4] Determination of kinetic and thermodynamic parameters of thermal degradation of different biomasses for pyrolysis
    Gouda, Narayan
    Panda, Achyut Kumar
    BIOCATALYSIS AND AGRICULTURAL BIOTECHNOLOGY, 2019, 21
  • [5] ADSORPTION OF MESOTRIONE IN SOILS: KINETIC AND THERMODYNAMIC PARAMETERS
    Chen, Tianming
    Yin, Chuntao
    Hu, Youbiao
    Cui, Liqiang
    Quan, Guixiang
    Ding, Cheng
    Yan, Jinlong
    FRESENIUS ENVIRONMENTAL BULLETIN, 2014, 23 (10A): : 2578 - 2585
  • [6] The Adsorption of Zn(II) Ions onto Chitin: Determination of Equilibrium, Kinetic and Thermodynamic Parameters
    Kocer, N. Nacer
    Uslu, G.
    Cuci, Y.
    ADSORPTION SCIENCE & TECHNOLOGY, 2008, 26 (05) : 333 - 344
  • [7] A thermal degradation study of disposable face mask wastes: determination of kinetic and thermodynamic parameters
    Kocer, A. T.
    Balkanli, D.
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2025, 22 (07) : 5399 - 5410
  • [8] DETERMINATION OF KINETIC AND THERMODYNAMIC PARAMETERS OF L-CYSTEINE ADSORPTION ONTO GOLD BY THE QCM TECHNIQUE
    dos Santos, Adriano
    da Silva, Josiel Jose
    Bueno, Paulo Roberto
    Watanabe, Ailton Massaiti
    QUIMICA NOVA, 2012, 35 (07): : 1365 - U488
  • [9] DETERMINATION OF EQUILIBRIUM, KINETIC AND THERMODYNAMIC PARAMETERS OF ACID RED 88 ADSORPTION ONTO MONTMORILLONITIC CLAY
    Dikmen, Sedef
    Gunay, Ahmet
    Ersoy, Bahri
    Erol, Ibrahim
    ENVIRONMENTAL ENGINEERING AND MANAGEMENT JOURNAL, 2015, 14 (05): : 1097 - 1110
  • [10] ADSORPTION OF FLUORIDE FROM AQUEOUS SOLUTIONS BY CARBON NANOTUBES: DETERMINATION OF EQUILIBRIUM, KINETIC, AND THERMODYNAMIC PARAMETERS
    Balarak, Davoud
    Mahdavi, Yosef
    Bazrafshan, Edris
    Mahvi, Amir Hossein
    Esfandyari, Yahya
    FLUORIDE, 2016, 49 (01) : 71 - 83
12345