Production of 2,5-hexanedione and 3-methyl-2-cyclopenten-1-one from 5-hydroxymethylfurfural

被引：61
|
作者：
Ren, Dezhang [1 ]
Song, Zhiyuan [1 ]
Li, Lu [1 ]
Liu, Yunjie [1 ]
Jin, Fangming [1 ]
Huo, Zhibao [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, State Key Lab Met Matrix Composites, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 10期
基金：
中国国家自然科学基金;
关键词：
FORMIC-ACID; HIGHLY EFFICIENT; REDUCTION; CO2; CONVERSION; TEMPERATURE; CATALYST; WATER; CYCLOPENTENONES; DISSOCIATION;
D O I：
10.1039/c5gc02493e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel approach for the production of 2,5-hexanedione (HDN) and 3-methyl-2-cyclopenten-1-one (3-MCO) from 5-hydroxymethylfurfural (HMF) by water splitting with Zn is reported for the first time. The use of high temperature water (HTW) conditions is the key for the efficient conversion of HMF to HDN and 3-MCO. Parameters regarding the Zn amount, temperature and reaction time are optimized and HDN and 3-MCO are produced in 27.3% and 30.5% yields, respectively. The roles of HTW and ZnO obtained by oxidation of Zn in water for the conversion of HMF, together with intermediate structures, are discussed to understand the mechanism of the reaction.
引用
收藏
页码：3075 / 3081
页数：7
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