Structural and photoluminescence studies of Eu3+ doped L-Tartaric single crystal through evaporation technique

被引:11
|
作者
Prasad, P. V. [1 ]
Rao, Tk Visweswara [1 ]
Kamal, Ch. Satya [1 ]
Lakshmi, S. Rajya [1 ]
Ramachandra, R. K. [1 ]
Sudarsan, V. [2 ]
Rao, M. C. [3 ]
SubbaRao, P. S. V. [4 ]
机构
[1] Govt Coll A, Dept Phys, Crystal Growth & Nano Sci Res Ctr, Rajahmundry 533105, Andhra Pradesh, India
[2] Baba Atom Res Ctr, Div Chem, Bombay, Maharashtra, India
[3] Andhra Loyola Coll, Dept Phys, Vijayawada, India
[4] Andhra Univ, Dept Phys, Visakhapatnam, Andhra Pradesh, India
关键词
L-Tartaric acid; Europium ions; HRXRD; Photoluminescence; Lifetime component; GROWTH; ACID; TARTRATE; PROGRESS;
D O I
10.1016/j.molstruc.2014.12.086
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Europium doped L-Tartaric acid; a non-linear optical single crystal was grown by slow evaporation solution growth method. The grown crystal was characterized by XRD for phase analysis, HRXRD for crystalline perfection, functional group by FTIR spectroscopy and powder SHG measurement for getting an estimate of NLO efficiency. The emission spectrum of Eu3+ doped L-Tartaric acid obtained after excitation at 394 nm and corresponding excitation spectrum by monitoring at 615 nm emissions. The decay curve is recorded corresponding to the D-5(0) level of Eu3+ from tartaric acid doped with europium ions. The transparency of the crystal shows >90%, thermal analysis shows that the crystal to be thermally stable up to 189 degrees C and estimated atomic elemental composition in grown crystal with EDAX. L-Tartaric acid with chiral structure acts as a good host material for probing Eu3+ ions in synthesis of luminescent materials. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:115 / 120
页数:6
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