Synthesis, crystal structure and SHG effect of complex [Cd(CH3OC6H3OHCH=NC2H4OH)2Cl2].(1/2)C2H5OH

被引：0

作者：

Cui, XG ^{[1
]}

Hu, QP ^{[1
]}

Gong, J ^{[1
]}

机构：

[1] Shandong Univ, Coll Chem, Jinan 250100, Peoples R China

来源：

ACTA CHIMICA SINICA | 1999年 / 57卷 / 02期

关键词：

cadmium complex; crystal structure; SHG effect;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex [Cd(CH3OC6H3OHCH = NC2H4OH)(2)Cl-2].(1/2)C2H5OH was synthesized and characterized by elemental analyses, IR as well as UV spectroscopy. Its structure was confirmed by single crystal X-ray diffraction, The complex crystal belongs to the monocline space group is C-c, with cell parameters: a = 1.5475(3), b =1.1661(2), c = 1.7295(3) nm, beta = 116.50(3)degrees, Z = 4, final R = 0.043 for 2261 unique reflections [ I greater than or equal to 3 sigma (I)]. The structure was solved by direct method. The results indicate that each of the cadmium atoms was coordinated with four oxygen atoms (from two ligands respectively), and two chlorine anions to form a twisted octahedron. The complex has a high SHG efficiency.

引用

页码：189 / 195

页数：7