Cu(I)-catalyzed cyclized coupling reaction of o-ethynylphenylphosphonic acid monoesters with allyl bromide

被引：12
|
作者：
Wei, P [1 ]
Ding, YX [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
来源：
SYNLETT | 2005年 / 04期
关键词：
phosphaisocoumarin; bioactivity; o-ethynylphenylphosphonic; acid monoester; cyclization; coupling;
D O I：
10.1055/s-2005-863717
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
4-Allylphosphaisocoumarins can be prepared in good yield and with high regioselectivity by the reaction of o-ethynyl-phenylphosphonic acid monoesters with allyl bromide catalyzed by Cut. The present reaction represents the first example of a phosphonic acid monoester cyclized coupling reaction with alkyl halide.
引用
收藏
页码：599 / 602
页数：4
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