Synthesis, crystal structure and magnetic properties of a new macrocyclic binuclear copper(II) complex

被引：1
|
作者：
Li, Qing-Xiang [1 ]
Pan, Zhi-Quan [1 ]
He, Bing-Zhong [1 ]
Xiao, Hai-Yan [1 ]
机构：
[1] Wuhan Inst Technol, Hubei Key Lab Novel Chem Reactor & Green Chem Tec, Wuhan 430073, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 06期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1007/s11243-007-0275-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new binuclear copper complex [CuLCl2](2), [L = 1-(p-tolylsulfonyl)-1,4,7- triazacyclononane], has been synthesized and structured as well as magnetically characterized. In the complex, each copper(II) atom is located in the center of a distorted square pyramidal configuration of five coordinating atoms (two nitrogen atom and three chlorine atom). Two copper(II) atoms were bridged by two chlorine anions (Cl1 and Cl1a). The distance between two copper(II) atoms is 3.483 a. An antiferromagnetic exchange coupling effect exists in the complex.
引用
收藏
页码：835 / 838
页数：4
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