Ruthenium porphyrin catalysed intermolecular amino-oxyarylation of alkenes to give primary amines via a ruthenium nitrido intermediate

被引：8

作者：

Yu, Daohong ^{[1
,2
]}

Shing, Ka-Pan ^{[3
,4
,5
]}

Liu, Yungen ^{[1
]}

Liu, Haiyang ^{[2
]}

Che, Chi-Ming ^{[1
,3
,4
,5
]}

机构：

[1] Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

[2] South China Univ Technol, Dept Chem, Guangzhou 510641, Guangdong, Peoples R China

[3] HKU Shenzhen Inst Res & Innovat, Shenzhen 518057, Guangdong, Peoples R China

[4] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

[5] Univ Hong Kong, State Key Lab Synthet Chem, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 01期

基金：

中国博士后科学基金;

关键词：

ASYMMETRIC AMINOHYDROXYLATION; BOND-CLEAVAGE; NITROGEN ATOM; SCHIFF-BASE; COMPLEXES; AZIRIDINATION; AMINATION; OLEFINS; ACTIVATION;

D O I：

10.1039/c9cc08043k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium porphyrin catalysed direct intermolecular amino-oxyarylation of alkenes including styrenes and 1,3-dienes to give primary amines with O-(2,4-dinitrophenyl)hydroxylamine as the amine source was achieved in moderate to good yields under mild reaction conditions. Spectroscopic analyses revealed that a ruthenium nitrido complex was the key reaction intermediate for the amino-oxyarylation reaction.

引用

页码：137 / 140

页数：4