Controllable Synthesis of Stereoregular Polyesters by Organocatalytic Alternating Copolymerizations of Cyclohexene Oxide and Norbornene Anhydrides

被引：92
|
作者：
Han, Bing [1 ]
Zhang, Li [1 ]
Liu, Binyuan [1 ]
Dong, Xiaofang [1 ]
Kim, Il [2 ]
Duan, Zhongyu [1 ]
Theato, Patrick [3 ]
机构：
[1] Hebei Univ Technol, Dept Polymer Sci & Engn, Tianjin 300130, Peoples R China
[2] Pusan Natl Univ, Dept Polymer Sci & Engn, WCU Ctr Synthet Polymer Bioconjugate Hybrid Mat, Busan 609735, South Korea
[3] Univ Hamburg, Inst Tech & Macromol, D-20146 Hamburg, Germany
来源：
MACROMOLECULES | 2015年 / 48卷 / 11期
基金：
新加坡国家研究基金会; 中国国家自然科学基金;
关键词：
RING-OPENING POLYMERIZATION; N-HETEROCYCLIC CARBENES; CYCLIC ACID ANHYDRIDES; THIOL-ENE CHEMISTRY; PROPYLENE-OXIDE; PHTHALIC-ANHYDRIDE; MALEIC-ANHYDRIDE; ZWITTERIONIC POLYMERIZATION; UNSATURATED POLYESTERS; ALIPHATIC POLYESTERS;
D O I：
10.1021/acs.macromol.5b00555
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A facile strategy has been demonstrated for the selective synthesis of highly stereoregular polyesters with cis-2,3-(exo, exo) or trans-2,3-(exo, endo) repeating units by the organocatalysts mediated alternating copolymerization of cyclohexene oxide and norbornene anhydride (NA) stereoisomers. The geometrical structure of polyester can be tuned simply by modulating the type of NA isomers (endo- or exo-NA), monomer feed ratio, and reaction temperature. The cis- (>99%) and trans-polyesters (>99%) exhibit high glass transition temperature up to 129.8 and 115.9 degrees C, respectively. The resulting polyesters provide a versatile platform to incorporate various functional groups through the robust thiol-ene reaction of the pendant norbornenyl groups.
引用
收藏
页码：3431 / 3437
页数：7
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