A fuel cell type gas sensor based on Pt/NbN for highly selective detection of hydrogen sulfide

被引:11
|
作者
Huang, Chaozhu [1 ,3 ]
Zhao, Jingwei [1 ,2 ]
Qu, Fengdong [1 ]
Wang, Jiacheng [4 ]
Yang, Minghui [1 ,3 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China
[2] Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[4] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 201899, Peoples R China
基金
中国国家自然科学基金;
关键词
Mesoporous NbN; Selectivity; Gas sensors; Hydrogen sulfide; Room temperature; METAL NITRIDE MATERIALS; METHANOL OXIDATION; CO; PERFORMANCE; DURABILITY;
D O I
10.1016/j.snb.2021.130516
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Hydrogen sulfide (H2S) is considered a highly hazardous toxic gas. H2S sensors are therefore of paramount significance for real-time leak detection. However, existing solutions do not meet the strict performance targets set by stakeholders, while deactivation due to surface area of sensing materials decrease and contamination is a widely unsolved problem. Presented here is a new support material, mesoporous niobium nitride (NbN), which improve the long-term stability largely via enhancing the interaction between metal and support. Simultaneously, sensor devices using NbN as support show enlarged sensitivity, enhanced limit of detection and well repeatability when compared with these sensors using traditional carbon black support. In a wider perspective, our work suggests strategies for enhancing long-stability of next-generation chemical gas sensors by optimizing metal-support interaction.
引用
收藏
页数:8
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